Background.- Palladium 1,2-migration in the Heck reaction.- Palladium 1,2-migration in the Negishi and Kumada coupling.- Stoichiometric studies on the palladium 1,2-migration.- Heteroaromatic tosylates in the regio-selective Heck reaction.- Cationic intermediates in the Ni(0)-catalyzed Heck...
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Background.- Palladium 1,2-migration in the Heck reaction.- Palladium 1,2-migration in the Negishi and Kumada coupling.- Stoichiometric studies on the palladium 1,2-migration.- Heteroaromatic tosylates in the regio-selective Heck reaction.- Cationic intermediates in the Ni(0)-catalyzed Heck reaction.- Carbonylative Heck reaction.- Conclusions.
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